全文获取类型
收费全文 | 19829篇 |
免费 | 3464篇 |
国内免费 | 3196篇 |
专业分类
化学 | 15081篇 |
晶体学 | 216篇 |
力学 | 1118篇 |
综合类 | 220篇 |
数学 | 2537篇 |
物理学 | 7317篇 |
出版年
2024年 | 20篇 |
2023年 | 375篇 |
2022年 | 470篇 |
2021年 | 630篇 |
2020年 | 809篇 |
2019年 | 864篇 |
2018年 | 656篇 |
2017年 | 668篇 |
2016年 | 944篇 |
2015年 | 1021篇 |
2014年 | 1210篇 |
2013年 | 1523篇 |
2012年 | 1792篇 |
2011年 | 1831篇 |
2010年 | 1372篇 |
2009年 | 1411篇 |
2008年 | 1435篇 |
2007年 | 1248篇 |
2006年 | 1142篇 |
2005年 | 979篇 |
2004年 | 830篇 |
2003年 | 742篇 |
2002年 | 764篇 |
2001年 | 575篇 |
2000年 | 450篇 |
1999年 | 426篇 |
1998年 | 320篇 |
1997年 | 278篇 |
1996年 | 274篇 |
1995年 | 211篇 |
1994年 | 189篇 |
1993年 | 196篇 |
1992年 | 135篇 |
1991年 | 132篇 |
1990年 | 107篇 |
1989年 | 90篇 |
1988年 | 78篇 |
1987年 | 52篇 |
1986年 | 49篇 |
1985年 | 49篇 |
1984年 | 29篇 |
1983年 | 23篇 |
1982年 | 27篇 |
1981年 | 12篇 |
1979年 | 7篇 |
1978年 | 6篇 |
1977年 | 6篇 |
1976年 | 4篇 |
1973年 | 4篇 |
1972年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
71.
Using first-principle calculations, mechanical properties, electronic structure, and Raman spectra of LiB6Si structure were investigated. The band structures calculated by GGA-PBE and HSE06 methods reveal that LiB6Si is an indirect band gap semiconductor. The band gap estimated by HSE06 method is about 2.24 eV, which is in good agreement with that of experimental value 2.27 eV. The calculated tensile stress-strain curves of LiB6Si reveal that [010] direction is the cleavage direction under tensile strains. The calculated Raman spectra of LiB6Si are also in good agreement with that of measured. The position of the band gap may provide a basis for further photocatalysis research on LiB6Si. 相似文献
72.
Flexible control of building blocks of photonic crystals enables achieving desirable band structures. Exploration of photonic band extrema has brought many fantastic features to design artificial optical materials, such as Brillouin‐zone‐corner extrema for valley photonic materials and zone‐center extremum for zero‐index metamaterials. However, two such kinds of extrema are always found independently in different photonic crystals. In this work, a kind of valley photonic crystals possessing both zone‐center and zone‐corner band extrema almost at the same frequency is proposed. Inspired by antennas theory, a three‐antenna array (TAA) source is devoted to individually manipulate each extremum. The correlation coefficient is given to determine the coupling efficiency between the TAA source and extrema eigenmodes. By using a source with a high correlation coefficient, these extrema bulk states are selectively excited consistent with their eigenfields. Furthermore, three control cases are shown that multiple extrema points are simultaneously excited, in order to confirm the validity of the correlation coefficient. Finally, a potential application of a beam‐steering device is proposed through selective excitation of ternary extrema. This work develops binary valley states into ternary mix states, rendering more degrees of freedom for on‐chip optical information transport, particularly for beam steering and mode division multiplexing. 相似文献
73.
Rong Yin Jihui Zhang Xudong Shang 《Mathematical Methods in the Applied Sciences》2020,43(15):8736-8752
This paper is dedicated to studying the following Schrödinger–Poisson system Under some different assumptions on functions V(x), K(x), a(x) and f(u), by using the variational approach, we establish the existence of positive ground state solutions. 相似文献
74.
As a large group of cells in a central nervous system, astrocytes have a great influence on ion and energy metabolism in a nervous system. Disorders of neuronal ion and energy metabolism caused by impaired astrocytes play a key role in the pathogenesis of epilepsy. This paper reviews the existing computational models of epileptogenesis resulting from impaired astrocytes and presents several open perspectives with regard to ion and energy metabolism-induced epileptogenesis in a neuron-astrocyte-capillary coupled model. 相似文献
75.
Design of diamond-shape photonic crystal fiber polarization filter based on surface plasma resonance effect 下载免费PDF全文
A novel plasmonic polarization filter based on the diamond-shape photonic crystal fiber(PCF) is proposed. The resonant coupling characteristics of the PCF polarization filter are investigated by the full-vector finite-element method. By optimizing the geometric parameters of the PCF, when the fiber length is 5 mm, the polarization filter has a bandwidth of 990 nm and an extinction ratio(ER) of lower than -20 dB. Moreover, a single wavelength polarization filter can also be achieved, along with an ER of -279.78 dB at wavelength 1.55 μm. It is believed that the proposed PCF polarization filter will be very useful in laser and optical communication systems. 相似文献
76.
本文采用关联分析方法研究了稳定温度分层湍流中的结构特性、输运特性,以及热量、动量逆梯度输运现象的尺度效应及其参数演化.首先采用大涡模拟方法对稳定分层湍流中的结构特性和输运特性进行了分析,将逆梯度输运发生的时间尺度作为已知条件,结合关联量分析方法在波数空间中的解析解,对逆梯度输运现象的尺度效应进行了分析研究.结果发现,稳定分层强度较大的流动中发生垂向热量及动量逆梯度输运现象,发生的结构尺度与关联分析所发现垂向热量、动量逆梯度输运的波数形成了呼应.随着分层强度增加,热量、动量的输运强度均受抑制,与逆梯度输运关联的流场结构尺度减小,同样的效应也发生在流场结构向下游演化的过程中. 相似文献
77.
78.
We demonstrated a femtosecond mode-locked Er:Zr F4-Ba F2-La F3-Al F3-Na F(Er:ZBLAN)fiber laser at 2.8μm based on the nonlinear polarization rotation technique.The laser generated an average output power of 317 m W with a repetition rate of 107 MHz and pulse duration as short as 131 fs.To the best of our knowledge,this is the shortest pulse generated directly from a mid-infrared mode-locked Er:ZBLAN fiber laser to date.Numerical simulation and experimental results confirm that reducing the gain fiber length is an effective way to shorten the mode-locked pulse duration in the Er:ZBLAN fiber laser.The work takes an important step towards sub-100-fs mid-infrared pulse generation from mode-locked Er:ZBLAN fiber lasers. 相似文献
79.
Yue Gu Rongrong Yuan Xiaoyi Yan Cong Li Weilu Liu Ruixue Chen Liu Tang Bo Zheng Yaru Li Zhiquan Zhang Ming Yang 《Analytica chimica acta》2015
Hole-transporting materials with tunable structures and properties are mainly applied in organic light-emitting diodes as transport layer. But their catalytic properties as signal amplifiers in biological assays are seldom reported. In this paper, a starburst molecule, 4,4,4″-tri(N-carbazolyl)-triphenylamine (TCT), containing a triphenylamine as the central core and three carbazoles as the peripheral functional groups was designed and synthesized. Subsequently, the hole-transporting material based on the TCT polymer, poly(TCT) (PTCT), was achieved via a low-cost electrochemical method and exploited as an efficient metal-free electrocatalyst for non-enzymatic glucose detection. Here, this hole-transporting material served three purposes: electrochemical recognition (owing to hydrogen bonding interaction and the biomimetic microenvironment created by the polymer), electrocatalysis (owing to the hole-transporting capability of triphenylamine and the catalytic property of carbazole), and signal amplification (owing to energy migration along the conductive polymer backbone). The electrocatalytic and sensing performances of the sensor based on PTCT were evaluated in detail. Results revealed that the PTCT film could efficiently catalyze the oxidation of glucose at a less-positive potential (+0.20 V) in the absence of any enzymes. The response to glucose was linear in the concentration range of 1.0–6000 μM, and the detection limit was 0.20 μM. With good stability and selectivity, the proposed sensor could be feasibly applied to detect glucose in practical samples. The encouraging sensing performances suggest that the hole-transporting material is one of the promising biomimetic catalysts for electrocatalysis and relevant fields. 相似文献
80.